I have nearly the same problem as you. My gf isn't able to enjoy sex as it hurts for her. Only difference is that my gf does want to, it just hurts for her.
Maybe your gf would have wanted to if it didn't hurt, but it's not the case so she associated sex to a painful experience and isn't interested (anymore).
What we did is go see a specialist (a 'sexologue' in French but I suppose it's the same in English) and she concluded that my gf has 'vaginisme' (fr). This means that she "locks herself up" whenever anything approaches her sexually (in this case, me) causing her vagina muscles to tend and makes it very tight, nearly impossible to enter.
Apparently, 'vaginisme' is caused by a sexual event that disgusted the girl (not necessarily penetration though) and made her a psychologic protection against sex, creating that "lock" mechanism. To make her enjoy sex again, you may need to see a therapist and find out what happened, why and how she can trust sex again. (I'm still and only talking about the 'vaginisme', I'm no doctor, I'm just saying what me and my gf have).
Good luck.