You're probably not warmed up/turned on enough before starting intercourse. When you're turned on enough and warmed up (and lubricated) sex should not hurt at all. It is a terrible myth that sex should be painful for the woman - the first time or anytime, it should not be painful.
I hate to be the bearer of bad news, but the solution is..... more foreplay! Haha. Just kidding. That's great news, isn't it!?!
Have oral sex (receiving it), and fingering for awhile to help warm you up. Lots and lots of foreplay. Also, buy a tube of lubricant. Many women don't naturally produce enough lubricant.