Anytime you have sexual intercourse, there is always a possibility of pregnancy. And since you did not use any protection at all (I'm assuming you are not on birth control pills) you run a rather high risk of becoming pregnant. It does not matter that he pulled out, pre-cum can get you pregnant as well.
You will have to wait and see if you miss your period, and if you do miss it, then take a test.
*edited for grammar