Of course it is possible, but the first time can be so painful for a woman that she may not be able to due to being a little uncomfortable.

She may be so anxious, or nervous that it is not possible for her either.

Of course a girl *can* have an orgasm the first time, even if it's unlikely. On the other hand, some women can have sex for years and never have one from intercourse.

Its possible just hard for several reasons.
First no matter how comfortable you are with the guy, your probably going to be tense and nervous the first time. You need to be relaxed to orgasm.
Second your body isn't used to how sex feels. I found the first time I was just trying to figure out what I was feeling (besides pain).
And lastly for most woman the first time hurts. For me, we couldn't finish, and he couldn't go all the way in the first time...Thus it was impossible.

The first time I doubt anyone's felt anything other than a slight to moderate amount of pain. I know it hurt horribly when I lost my virginity, but I think it was due to being nervous i'm not a very big person in general.

It didn't really hurt me but I didn't have an orgasm for about 2 1/2 years after my first time.Then after the first time I had one I didn;t have another until about a month ago and that took 2 more years. I think you just have to have the right person who knows what they are doing.

In maxim, there was a quote from a girl in there-she said "i've heard about girls who have never had an orgasm, and if that's you-masturbate when you're having sex and you'll be all set" she is so right. Why wait around for the right guy to give you what you want, when you can take care of yourself.