Ortho cept is the same as apri, cyclessa, mircette, and desogen. It is just a combined hormone drug, so the standard rules apply.
~First day of period start- Take it on the first day of bleeding, you are protected instantly.
~Sunday start- take it on sunday, you are protected after 7 days
~Any other day start- take it whenever the heck you want, you are protected after seven days.