It all depends if some semen got inside her. She is quite correct that a woman does not get pregnant every time she has sex. It also takes a considerable amount of sperm to get her pregnant, And she needs to be in her fertile week.
This is actually what emergency contraceptives like Plan B or Ella is for. It may be a good idea to get a single dose and keep it in her medicine cabinet for incase something happens. That way she can take it as soon as possible with the maximum effectivity.
After ejaculation you will lose your erection pretty quickly, causing you to slip out. The semen inside will also make it more slippery. So just grab it by your base and be done with it. Also look at it before disposing it to make sure it stayed intact.
Take care and please be careful.