Yes, it is possible for her to get pregnant at any point in her cycle. It is much less likely when it isn't around ovulation, but you don't know when she ovulates.
This may or may not be cause for concern. It sounds like you guys are young and sometimes girls have irregular cycles. It may be a little early for the test to tell, but go buy a pregnancy test together or, if you don't feel comfortable, ask an adult that you trust to do it. Remember, it is important for you guys to stay calm and work through this together.
If she is pregnant, talk calmly and rationally about what to do. Don't jump into any decisions out of fear. I know you might think that your parents will be angry or disappointed, and that may be true, but they can also provide important emotional support. You two should not have to go through this alone. I don't know what your family situation is, but your parents may be more understanding than you think.
If talking to your parents is out of the question, she can see her family doctor and he is required to keep the visit confidential.
***A final note: if she isn't pregnant, this is a lesson to always use protection. You should always use a condom to protect yourself, her, and to prevent pregnancy. A second form of birth control (such as the pill) would also be good because condoms do fail sometimes and aren't 100% effective.
Regardless of what happens, stick together and support each other.
All the best.