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Your first day of bleeding should have been taken as the first day when you got the dark brown bleeding (dried blood like discharge). If you are sure of the symptoms being pregnancy symptoms, and you have not used and back-up method of contraception during first month of use of Nuva ring, then chances of pregnancy are high. Hormonal contraceptives can result with giving you few symptoms resembling pregnancy. Other medications taken while being on the hormonal contraceptives can affect the efficacy of the hormonal contraceptives.
Look out for definite symptoms like breast pain, engorgement, nipple sensitivity, increased sleep, hunger and tiredness, increased fatigue, increased frequency of urination, mood changes, headaches, constipation, mild abdominal cramps, bloating etc.
Visit your gynecologist/healthcare provider to get examination done and request to get a blood beta HCG test done to confirm/rule out pregnancy as urine pregnancy tests can sometimes show false negative results.
Take care.