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Brown ring around areola or any other changes in the breasts can be due to the hormonal fluctuations occuring in the body.Since there is no other symptom as pain,lump,itching,fever it does not seem like an infection and might be symptoms of Menarche(starting of periods).During puberty girl undergoes hormonal changes in the body.This could also be the reason of her being too emotional.
Keep observing the ring at intervals.If there are any changes as pain,lump get it evaluated by your Healthcare Provider.
Take Care!